About Chemical Equilibrium
Chemical Equilibrium is a tool for accurate estimation of concentrations and pressures of the chemical reaction reactants and products at equilibrium. The application derives final, equilibrium parameters based on...
Chemical Equilibrium is a tool for accurate estimation of concentrations and pressures of the chemical reaction reactants and products at equilibrium. The application derives final, equilibrium parameters based on equilibrium constants (Kc and Kp), initial concentrations and stoichiometric coefficients. Additionally, app calculates reaction quotient "Q" for any given concentrations and stoichiometry (Q in equilibrium is equal to Keq, so can be used for one-click calculation of Kc or Kp when all concentrations or pressures are at equilibrium!). The user may adjust stoichiometric coefficients to fit desired reaction, and set initial concentrations and equilibrium constant to run the calculations.
For a general chemical reaction:
aA + bB cC + dD,
the Reaction Quotient (Q) is defined by:
Q=(C^c*D^d)/(A^a *B^b );
where A, B, C, D – are compounds’ concentrations or pressures and a, b, c, d are stoichiometric coefficient*. Sum of powers determines the reaction order.
*Importantly, actual powers may differ from reaction coefficients, due to overall reaction mechanism complexity.
If Q is not equal to reaction equilibrium constant K (Kc for concentrations and Kp for pressures), then reaction is not at equilibrium and it will proceed (due to difference in forward and reverse reaction speeds) to the direction defined by Q.
If QK – reverse reaction will prevail.
Example:
For given reaction: 2A + 1B 3C + 2D , initial reaction concentrations are Ao=0.1M, Bo=0.2M, Co=0.3M and Do=0.4M and Kc=1 M2.
the Reaction Quotient (Q) is defined by:
Q=(Co^3*Do^2)/(Ao^2*Bo^1 )
upon q="">
The new equilibrium concentrations of reaction components can be derived from the equation:
Kc=((Co-3x)^3*(Do-2x)^2)/((Ao+2x)^2*(Bo+x))
Apparently, solving this equation is rather demanding task, that turns to be unnecessary, since “Chemical Equilibrium” app immediately returns the answer: Aeq=0.1185M, Beq=0.2092M, Ceq=0.2723M and Deq=0.3815M.
The application features:
To start calculation user is required to fill in stoichiometric coefficients, initial concentrations (pressures) of available components, and equilibrium constant Kc (Kp).
Reaction coefficients are actually representing powers and therefore define reaction order.
To start calculation initially or after updating the concentration or coefficient fields, user is requested to tap Run button!
Significant attention should be paid to concentration, pressure and equilibrium constant units. App automatically changes the set of available units as per order of reaction!
The basic conversions are as follows:
1 M= (1e3) mM
1 atm=101325 Pa
Previous Versions
Here you can find the changelog of Chemical Equilibrium since it was posted on our website on 2016-10-09 17:47:44.
The latest version is 2.7 and it was updated on 2024-04-19 22:22:17. See below the changes in each version.
Chemical Equilibrium version 2.7
Updated At: 2020-07-26
Disclaimer
Official Google Play Link
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